I'm a little fuzzy on exactly what you're saying, but I'll give it a stab.

It sound like you need to set up routes on your client workstations to two different 
networks. 

Assuming you have your gateway pointing to the application, try this in a command 
prompt

ROUTE ADD [destination] MASK [mask] [gateway] [metric] IF[interface]

Where destination is the network that you need to get to (in this case, the Internet)

Mask is the subnet mask of that network.

Gateway is the specific address that will get you to that network

Metric should probably be set at 1 or 2

Interface can probably be skipped, and it will see that the client only has one NIC.

These instructions are for Win2000, I think the command is even more basic for Win98. 
In a DOS (command) prompt, type ROUTE ADD and it will give you the syntax.

HTH,
Tim

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