It looks as if your control panel applet for User Accounts is corrupt. The file is 
nusrmgr.cpl and is in the Windows System32 folder. 

You can replace it like this:

Start . . . Run . . . msconfig

General tab, click on Expand File, and fill in the boxes as follows:

File to restore: nusrmgr.cpl

Restore From: enter the path to your XP or (if you have one) the i386 folder 
on your PC

Save file in C:\Windows\System32

Finally click on the Expand button.

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